Unlikely to be broken in the next 10–15 years unless rule changes heavily favor attackers.
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However, the all-time record for most goals in a La Liga season is: most goals in a la liga season
Telmo Zarra (38 goals in 1950–51) and Hugo Sánchez (38 in 1989–90) held the pre-Messi/Ronaldo record. Unlikely to be broken in the next 10–15